When accurate thermocouple measurements are required, it is common practice to reference both legs to copper lead wire at the ice point so that copper leads may be connected to the emf readout instrument due to the cold junction. This procedure avoids the generation of thermal emfs at the terminals of the readout instrument. Changes in reference junction temperature influence the output signal and practical instruments must be provided with a means to cancel this potential source of error.
The EMF generated is dependent on a difference in temperature, so in order to make a measurement the reference must be known. This is shown schematically in Fig. #1 and can be accomplished by placing the reference junction in an ice water bath at a constant 0°C (32°F). Because ice baths are often inconvenient to maintain and not always practical, several alternate methods are often employed.
The basic principle behind cold junction compensation is that you must know the cold junction temperature to calculate the hot junction temperature. This is because the voltage generated in a thermocouple circuit is proportional to the terminal difference between the hot and cold junction.
The governing equation for this is:
Eemf = −S∆T = S(THOT − TCOLD), where:
- Eemf is the voltage output of the thermocouple
- S is a temperature-dependent material property, known as the Seebeck coefficient (For a type K thermocouple, this is roughly 4.1 μV/°C between 0°C and 1000°C)
- TCOLD is the Temperature of the Cold Junction
- THOT is the Temperature of the Hot Junction (This is what you want to know!)
Rearranging this equation for THOT yields:
Techniques to compensates the cold junction
Electrical Bridge Method
This method usually employs a self-compensating cold junction
electrical bridge circuit as shown in Figure 2. This system incorporates
a temperature sensitive resistance element (RT), which is in one
leg of the bridge network and thermally integrated with the cold
junction (T2). The bridge is usually energized from a mercury
battery or stable d.c. power source. The output voltage is proportional
to the unbalance created between the pre-set equivalent reference
temperature at (T2) and the hot junction (T1). In this system,
the reference temperature of 0° or 32°F may be chosen.
As
the ambient temperature surrounding the cold junction (T2) varies,
a thermally generated voltage appears and produces an error in
the output. However, an automatic equal and opposite voltage is
introduced in series with the thermal error. This cancels the
error and maintains the equivalent reference junction temperature
over a wide ambient temperature range with a high degree of accuracy.
By integrating copper leads with the cold junction, the thermocouple
material itself is not connected to the output terminal of the
measurement device, thereby eliminating secondary errors.
Thermoelectric refrigeration method
The Omega¨ TRC Thermoelectric
ice pointTM Reference Chamber relies on the actual equilibrium
of ice and distilled, deionized water and atmospheric pressure
to maintain several reference wells at precisely 0°C. The wells
are extended into a sealed cylindrical chamber containing pure
distilled, deionized water.
The chamber outer walls are cooled
by thermoelectric cooling elements to cause freezing of the water
in the cell to work as a cold junction reference. The increase in volume produced by freezing an ice
shell on the cell wall is sensed by the expansion of a bellows
which operates a microswitch, de-energizing the cooling element.
The alternate freezing and thawing of the ice shell accurately
maintains a 0°C environment around the reference wells. An application
schematic is shown in Fig. #3.
Completely
automatic operation eliminates the need for frequent attention
required of common ice baths. Thermocouple readings may be made
directly from ice point reference tables without making corrections for reference
junction temperature.
Using a reference chamber
Portable Ice Point™ Calibration Reference Chamber
The new ice point™ reference chamber TRCIII-A is the latest addition to OMEGA’s fine line of calibration reference instrumentation. The TRCIII-A ice point™ reference chamber relies on the equilibrium of ice and distilled, deionized water at atmospheric pressure to maintain six reference wells at precisely 0°C.
Any combination of thermocouples may be used with this instrument by simply inserting the reference junctions in the reference wells. Calibration of other type temperature sensors at 0°C may be performed as well. Heated oven references: The double-oven type employs two temperature-controlled ovens to simulate ice-point reference temperatures as shown in Fig. 4. Two ovens are used at different temperatures to give the equivalent of a low reference temperature differing from the temperature of either oven.
For example, leads from a type K thermocouple probe are connected with a 150° oven to produce a Chromega¨-Alomega¨ and an Alomega-Chromega junction at 150°F (2.66 mV each).
The voltage between the output wires of the first oven will be twice 2.66 mV or 5.32 mV. To compensate for this voltage level, the output leads (Chromega and Alomega) are connected to copper leads within a second oven maintained at 265.5°F. This is the precise temperature at which Chromega-Copper and Alomega-Copper produce a bucking voltage of differential of 5.32 mV.
Thus, this voltage cancels out the 5.32 mV differential from the first oven leaving 0 mV at the Copper output terminals. This is the voltage equivalent of 32°F (0°C).